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Tuesday, November 13, 2007

Focusing Light on Silicon Beads

Placing tiny spheres of silicon in reflective trays could be the key to cheap, efficient solar cells.

By Duncan Graham-Rowe

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Silicon spheres: Making solar cells out of tiny spheres of silicon (top image, black) can reduce the amount of the material used to just one-fifth. Hexagonal reflectors (middle image) ensure that most of the light hits the spheres. A flexible foil base means that the solar cells can be shaped for different applications (bottom image).
Credit: Clean Venture 21

A company in Japan has developed a novel way of making solar cells that cuts production costs by as much as 50 percent. The photovoltaic (PV) cells are made up of arrays of thousands of tiny silicon spheres surrounded by hexagonal reflectors.

The key advantage of the system is that it reduces the total amount of silicon required, says Mikio Murozono, president of Clean Venture 21 (CV21), based in Kyoto, Japan. "We use one-fifth of the raw silicon material compared with traditional PV cells," he says.

This can make a huge difference to the overall cost of producing solar cells, says Howard Branz, principal scientist at the National Renewable Energy Laboratory's National Center for Photovoltaics, in Golden, CO. "About 20 to 30 percent of the cost of a solar-cell module is in the cost of the raw silicon," he says.

CV21 started production of its cells in October; the first of its 10-kilowatt modules go on sale this month. While these modules will initially cost about the same as the traditional variety, the price is set to drop by 30 percent in 2008, as production increases in May from 1,000 cells a day to 60,000 cells a day, says Murozono. The ultimate goal is to make them 50 percent cheaper than existing cells by 2010, he says.

Spherical solar cells were originally proposed by Texas Instruments about 30 years ago, says Branz. But while they had the potential to reduce the amount of silicon used, they brought with them a host of new problems. Their curved surfaces, for example, can cause more light to be reflected, which reduces their efficiency. What's more, only half of the sphere ends up actually being exposed to light. Significant gaps also tend to form between the spheres when arranged in arrays, which can further reduce the efficiency of the solar cell.

CV21's solution was to place each of the one-millimeter-diameter silicon spheres in its own hexagonal aluminium reflector. These work like car headlights but in reverse, ensuring that any light hitting the reflector is directed toward the sphere. When this approach is used, even the underside of the sphere is utilized. The hexagonal shape of the reflectors allows them to be slotted together without dead space between them. "Effectively, these are mini-concentrators," says Branz.

The spheres themselves consist of a positively doped (p-type) ball of silicon. The ball's surface is treated to make it negatively doped (n-type), and an antireflective coating is also added. These two outer layers form the basis of the photovoltaic semiconductor material. The spheres are then bonded to an electrode on a flexible foil substrate via a hole at the bottom of the reflector.

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Comments

  • promising, but...
    cripdyke on 11/13/2007 at 5:06 AM
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    Avg Rating:
    4/5
    there have been quite a number of techs promising to cut the cost in half....and some of them, especially nanosolar, are already doing it.

    Also, this doesn't seem to be particularly conducive to combining with other techniques that are just now ready to move out of the lab into the market. Some other techs are designed in such a way that they would still benefit from others' advances.

    What isn't noted, however, in the text is that the costs here are the costs of manufacture. The tech described, however, is perfectly positioned to save a bundle on installation as well. So...if they can achieve their 50% production cost, and the installation costs are further reduced, the relative ease of manufacture could allow them to build plants in multiple countries and reduce shipping & tariff costs leading to a genuinely competitive product.

    So, I give it a 6 out of 10 compared to other techniques that have just left the lab or just hit the market (and the ones in between, such as having finished R&D but the plant isn't up to full production yet).

    And what's nice is that it is indigenous to Japan - the other techs that rate higher than this one aren't. With their notable barriers to foreign competition, the Japanese gov't and MITI might be a significant barrier to the economic boost that solar pv will be getting elsewhere in the world ...unless local pv costs fall based on entirely japanese IP/manufacture.

    Nice to see that Japan won't (really: might not) be pumping out extra CO2 just because of MITI over the next 8 to 10 years.
    Rate this comment: 12345
  • Better Photovoltaics?
    ajimenez on 11/13/2007 at 10:56 AM
    Posts:
    14
    If the efficiency is not better and the price is not better and the durability is suspect, who's going to buy it? They better sell it at half price or stay out of the business--for everyone's sake.
    Rate this comment: 12345
  • Whither energy
    GaryB on 11/13/2007 at 6:23 PM
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    4/5
    It would be nice to see a semi-annual tracking of all these new technologies.  They all come on the scene promising various things and then most seem to just sink.  I wonder if some graph/spreadsheet could be published on all these solar (and bio-fuel) efforts. 

    With solar, you have many
    Heliovolt, First Solar, Nanosolar etc etc.  How are they doing? Where are they at?
    Rate this comment: 12345
    • Re: Whither energy
      cripdyke on 11/15/2007 at 6:46 PM
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      15
      Avg Rating:
      4/5
      nanosolar, in particular, is doing well. Their initial volume was all purchased in bulk (I believe by european customers). Thus they've been doing fine getting things rolling, but product still isn't generally available so sites haven't considered it newsworthy (they think: "We already told you they were doing it, so unless they fail or something new happens like the product hitting local retailers, why should we update?")

      But what I would really like to know is how things are going with combining technology/i.p. from different companies. If they can reach deals on how to share technology so 1 new product can get the benefit of both breakthroughs, prices can drop dramatically.
      Rate this comment: 12345
      • Re: Whither energy
        samlum on 12/02/2007 at 10:13 PM
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        1
        Your suggestion on combining talent/inventions is simple and good, unfortunely it will never happen. If people can work together for the common good, this will be a much better world.
        Rate this comment: 12345
  • The promise is in the raw materials
    asdar on 11/14/2007 at 9:36 AM
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    4/5
    CIGS and standard silicon both have some raw material problems.

    Right now CIGS can be produced cheaply, but how about when Galium and Selenium start to feel the crunch.

    Silicon shouldn't be that much of a long term problem, but if we're making a true push toward solar we're going to need a hundred times what we're using now, not even mentioning the still blooming computer usage of silicon in China and India.

    Demand will most likely continue to rise, and supply might be under a crunch.

    Plus, this is technology. Maybe it will lead to something else.
    Rate this comment: 12345
  • Costs
    Spothannah on 11/14/2007 at 11:32 AM
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    1
    It seems that the cost of solar cells per unit of usable electricty keeps comming down while the cost of oil (not counting the environmental or social or political costs) continues to climb. Isn't it just a matter of time before "oil" becomes obsolete as a means of producing most of our energy?
    Rate this comment: 12345
    • Re: Costs
      TimG on 11/14/2007 at 7:42 PM
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      Avg Rating:
      3/5
      Exactly.  With the storage capacity and cost-effectiveness of batteries coming down and solar cells becoming more affordable, a convergence is coming that will lead to a revolution.  Put a solar panel bank on the roof and an electric car in the garage and you can basically forget about high oil prices!
      Rate this comment: 12345
  • Allied with the news from IBM
    weee on 11/15/2007 at 4:27 AM
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    33
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    3/5
    that it has developed an effective process that enables waste silicon to be made available for solar power - http://www-03.ibm.com/press/us/en/pressrelease/22504.wss
    The news is looking very good indeed - if the cost savings are passed through to consumers; installing solar power will pay for itself in less than 5 years in a sunny climate and 10 years in the UK.
    Rate this comment: 12345
  • Contact Silacon and LANL.gov
    Silacon on 11/15/2007 at 11:18 AM
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    2/5
    Dear clever people:

    Our company, Silacon, in association with Los Alamos National Laboratory invented a similar array that is useful for PV and blast absorption. Your idea should move to LANL.gov. 
    Rate this comment: 12345
  • this has been around a long time
    anon on 11/16/2007 at 9:55 AM
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    1
    there was a Canadian company that spent $170 mn trying to make this work and failed.  All these attempts to save on silicon material costs are useless if the resultant cell is only 2% less on efficiency. cost of silicon @ $70/kg = $0.50 / Wp.  At $6/Wp installed, 1% efficiency loss equals $0.37 at an average 15% cell. Lose more than 1.3% on efficiency, and even free silicon would not make your cells competitive.
    Rate this comment: 12345
  • assembly costs
    ess on 11/18/2007 at 8:47 PM
    Posts:
    1
    It seems that the cost of the complex reflectors, the attachment of the silicon spheres, the wiring, etc. will be an issue.  Also, is the whole assembly to be potted in a transparent sealant?  if not, the dust collection will quickly reduce efficiency and the array will be difficult to clean up.
    Rate this comment: 12345
    • Re: assembly costs
      v-man on 12/11/2007 at 12:46 PM
      Posts:
      1
      {CV21 started production of its cells in October; the first of its 10-kilowatt modules go on sale this month.}

      Wow! I guess they ship these 10kw modules on really BIG trucks?
      Rate this comment: 12345
  • Silicon Beads
    simonebottan on 11/14/2008 at 12:07 PM
    Posts:
    1
    I just jumped by accident on this paper, while searching for the available technologies to produce different sizes of silicon beads: this is what my research project carried me to deal with...
    So,
    does anybody know how these guys produce the mentioned 1 mm diameter silicon beads? And what kind of silicon is used for these energy applications?
    Rate this comment: 12345
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